Poly[diaqua-μ2-oxalato-di-μ4-terephthalato-diytterbium(III)]

نویسندگان

  • Chun-Xiang Wang
  • Zhi-Feng Li
چکیده

The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol-ecules. The Yb(3+) ion has a distorted square-anti-prismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O-H⋯O hydrogen bonding with both terephthalate anions.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010